Cover Feature: New Water‐Soluble Cluster Compound {Zn(en)3}3[V15Sb6O42(H2O)]⋅ (Ethylenediamine)3⋅10 H2O as a Synthon for the Generation of Two New Antimonato Polyoxovanadates (Chem. Eur. J. 21/2018). Issue 21 (19th February 2018)

• Record Type: Journal Article
• Authors: Mahnke, Lisa K.; Warzok, Ulrike; Lin, Mengxi; Näther, Christian; Schalley, Christoph A.; Bensch, Wolfgang
• Is Part Of: Chemistry. Volume 24:Issue 21(2018)
• Page Start: 5399
• Page End: 5399
• Publication Date: 2018-02-19
• Subjects: cluster compounds -- crystal structure -- ESI-MS -- solvothermal synthesis -- water-soluble precursor; Chemistry -- Periodicals; 540
• DOI: 10.1002/chem.201800471
• Languages: English
• ISSNs: 0947-6539

Abstract

Abstract : A new compound featuring the {V15 Sb6 O42 } core exhibits a remarkable solubility and stability in water. Electrospray ionization mass spectrometry (ESI‐MS) provides evidence of the slow transformation into a more vanadium‐poor and more antimony‐rich compound. Applying the new {V15 Sb6 O42 } compound as a synthon, two additional and new antimonato‐polyoxovanadate compounds containing the {V15 Sb6 O42 } cluster could be synthesized within a short reaction time of 24 h. More information can be found in the Full Paper by W. Bensch et al. onpage 5522 .