Modeling Transport of Cesium in Grimsel Granodiorite With Micrometer Scale Heterogeneities and Dynamic Update of Kd. Issue 11 (16th November 2017)

• Record Type: Journal Article
• Authors: Voutilainen, Mikko; Kekäläinen, Pekka; Siitari‐Kauppi, Marja; Sardini, Paul; Muuri, Eveliina; Timonen, Jussi; Martin, Andrew
• Is Part Of: Water resources research. Volume 53:Issue 11(2017)
• Page Start: 9245
• Page End: 9265
• Publication Date: 2017-11-16
• Subjects: diffusion -- sorption -- transport modeling -- Time Domain Random Walk -- crystalline rock -- X‐ray tomography; Hydrology -- Periodicals; 333.91
• DOI: 10.1002/2017WR020695
• Languages: English
• ISSNs: 0043-1397

Abstract

Abstract: Transport and retardation of cesium in Grimsel granodiorite taking into account heterogeneity of mineral and pore structure was studied using rock samples overcored from an in situ diffusion test at the Grimsel Test Site. The field test was part of the Long‐Term Diffusion (LTD) project designed to characterize retardation properties (diffusion and distribution coefficients) under in situ conditions. Results of the LTD experiment for cesium showed that in‐diffusion profiles and spatial concentration distributions were strongly influenced by the heterogeneous pore structure and mineral distribution. In order to study the effect of heterogeneity on the in‐diffusion profile and spatial concentration distribution, a Time Domain Random Walk (TDRW) method was applied along with a feature for modeling chemical sorption in geological materials. A heterogeneous mineral structure of Grimsel granodiorite was constructed using X‐ray microcomputed tomography (X‐μCT) and the map was linked to previous results for mineral specific porosities and distribution coefficients ( Kd ) that were determined using C‐14‐PMMA autoradiography and batch sorption experiments, respectively. After this the heterogeneous structure contains information on local porosity and Kd in 3‐D. It was found that the heterogeneity of the mineral structure on the micrometer scale affects significantly the diffusion and sorption of cesium in Grimsel granodiorite at the centimeter scale. Furthermore, the modeled in‐diffusion profiles and spatial concentration distributions show similar shape and pattern to those from the LTD experiment. It was concluded that the use of detailed structure characterization and quantitative data on heterogeneity can significantly improve the interpretation and evaluation of transport experiments. Key Points: Heterogeneous mineral structure has a significant effect to transport of cesium in Grimsel granodiorite Time Domain Random Walk modeling in heterogeneous rock was able to reproduce similar diffusion profiles as in situ experiments Experimental structure characterization methods are essential when creating geometries for transport modeling