Atom-economical, room-temperature, and high-efficiency synthesis of polyamides via a three-component polymerization involving benzoxazines, odorless isocyanides, and water. Issue 47 (8th November 2018)

• Record Type: Journal Article
• Authors: Zhang, Jie; Shi, Wei; Liu, Qiao; Chen, Tinglu; Zhou, Xinyu; Yang, Chang; Zhang, Kesong; Xie, Zhengfeng
• Is Part Of: Polymer chemistry. Volume 9:Issue 47(2018)
• Page Start: 5566
• Page End: 5571
• Publication Date: 2018-11-08
• Subjects: Polymers -- Periodicals; Macromolecules -- Periodicals; Polymerization -- Periodicals; 547.705
• DOI: 10.1039/c8py01256c
• Languages: English
• ISSNs: 1759-9954

Abstract

Abstract : High-efficiency three-component polymerization involving benzoxazines, odorless isocyanides, and water to synthesize polyamide derivatives at room temperature was reported here. Abstract : A novel octylphosphonic acid (OPA)-catalyzed, high-efficiency, three-component polymerization system involving benzoxazines, odorless isocyanides, and water was developed to synthesize polyamide derivatives with satisfactory molecular weights. This polymerization system showed the advantages of atom-economy, wide substrate scope, short reaction time (6 h), atmosphere-insensitivity, and mild reaction conditions (metal-free catalyst and room temperature).