Dicarboxamide polymorph derivatives for trace-level electrochemical sensing of Cu(ii) supported with crystal structure and theoretical studies. Issue 47 (16th November 2018)

• Record Type: Journal Article
• Authors: Rana, Love Karan; Sharma, Rashmi; Ahmed, Bilal; Kaur, Damanjeet; Kumar, Sanjeev; Hundal, Geeta; Mittal, Susheel K.
• Is Part Of: Analytical methods. Volume 10:Issue 47(2018)
• Page Start: 5643
• Page End: 5648
• Publication Date: 2018-11-16
• Subjects: Chemistry, Analytic -- Periodicals; Analytical biochemistry -- Periodicals; Chemical laboratories -- Standards -- Periodicals; 543.1905
• DOI: 10.1039/c8ay01967c
• Languages: English
• ISSNs: 1759-9660

Abstract

Abstract : A polymorph of fully substituted pyridine dicarboxamideL3 has been utilized to explore its cation-sensing ability using voltammetric experiments. Abstract : A polymorph of fully substituted pyridine dicarboxamideL3 has been utilized to explore its cation-sensing ability using voltammetric experiments. It has been observed that among the twelve metals employed for sensing comprising a mixture of transition and alkaline earth metals, a selective response to Cu(ii ) ions is obtained. The sensing phenomenon is further assisted by theoretical studies, which explain the high selectivity ofL3 for Cu(ii ) ions relative to other metal ions considered for experimental study.