High performance zinc-bromine redox flow batteries: Role of various carbon felts and cell configurations. (December 2018)

• Record Type: Journal Article
• Authors: Suresh, S.; Ulaganathan, M.; Venkatesan, N.; Periasamy, P.; Ragupathy, P.
• Is Part Of: Journal of energy storage. Volume 20(2018)
• Page Start: 134
• Page End: 139
• Publication Date: 2018-12
• Subjects: Zinc bromine -- Flow battery -- Carbon felt -- Efficiency; Energy storage -- Periodicals; Energy storage -- Research -- Periodicals; 621.3126
• DOI: 10.1016/j.est.2018.09.006
• Languages: English
• ISSNs: 2352-152X

Abstract

Graphical abstract: Highlights: Development of Zn-Br2 redox flow batter using different cell configuration Effective Zn utilization. Improved Bromine reversibility was achieved by altering the cell configuration. Improved energy density at 40 mA/cm 2 was also achieved using Rayon carbon felt. The flow cell exhibited good performance in terms of columbic (96.26%), voltaic (83%) and energy efficiency (79.4%). Abstract: Optimization of the cell configuration utilizing various carbon felts for obtaining better performance in zinc-bromine redox flow battery (ZBRFB) system is reported. It is clearly observed that the reaction kinetics of both Zn and Br are enhanced when used in different cell configurations with carbon felts. Redox flow cells having carbon felts on both half-cells showed improved performance thanthe other cell configurations tested in the present study. Further, Rayon based carbon felt is evaluated as an electrode on both sides. It is noted that the Rayon carbon felt based cell exhibited good performance in terms of coulombic (96.26%), voltaic (83%) and energy efficiency (79.4%) at a current density of 20 mA.cm −2 . In addition to that, Rayon felt based system showed good performance even at 40 mA.cm −2 (3250 mW h. l −1 ) which indicates the significance of the flow cell configuration on the overall cell performance.