Engineering the Electrical Conductivity of Lamellar Silver‐Doped Cobalt(II) Selenide Nanobelts for Enhanced Oxygen Evolution. Issue 1 (29th November 2016)

• Record Type: Journal Article
• Authors: Zhao, Xu; Zhang, Hantao; Yan, Yu; Cao, Jinhua; Li, Xingqi; Zhou, Shiming; Peng, Zhenmeng; Zeng, Jie
• Is Part Of: Angewandte Chemie international edition. Volume 56:Issue 1(2017)
• Page Start: 328
• Page End: 332
• Publication Date: 2016-11-29
• Subjects: cation exchange reaction -- electrical conductivity -- electrocatalysis -- nanostructures -- oxygen evolution reaction; Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201609080
• Languages: English
• ISSNs: 1433-7851

Abstract

Abstract: Precisely engineering the electrical conductivity represents a promising strategy to design efficient catalysts towards oxygen evolution reaction (OER). Here, we demonstrate a versatile partial cation exchange method to fabricate lamellar Ag‐CoSe2 nanobelts with controllable conductivity. The electrical conductivity of the materials was significantly enhanced by the addition of Ag + cations of less than 1.0 %. Moreover, such a trace amount of Ag induced a negligible loss of active sites which was compensated through the effective generation of active sites as shown by the excellent conductivity. Both the enhanced conductivity and the retained active sites contributed to the remarkable electrocatalytic performance of the Ag‐CoSe2 nanobelts. Relative to the CoSe2 nanobelts, the as‐prepared Ag‐CoSe2 nanobelts exhibited a higher current density and a lower Tafel slope towards OER. This strategy represents a rational design of efficient electrocatalysts through finely tuning their electrical conductivities. Abstract : Conducting materials : Silver‐doped cobalt(II) selenide (Ag‐CoSe2 ) nanobelts have been synthesized. Their electrocatalytic properties for the oxygen evolution reaction were studied ( j ( η =0.35 V)=current density at an overpotential of 0.35 V).