Novel way of phase stability of LSGM and its conductivity enhancement. (5th January 2015)

• Record Type: Journal Article
• Authors: Biswal, Ramesh Chandra; Biswas, Koushik
• Is Part Of: International journal of hydrogen energy. Volume 40:Number 1(2015)
• Page Start: 509
• Page End: 518
• Publication Date: 2015-01-05
• Subjects: SOFC -- LSGM -- Impedance spectroscopy -- XPS -- Pechini method; Hydrogen as fuel -- Periodicals; Hydrogène (Combustible) -- Périodiques; Hydrogen as fuel; Periodicals; 665.81
• DOI: 10.1016/j.ijhydene.2014.10.099
• Languages: English
• ISSNs: 0360-3199

Abstract

Abstract: Instead of using various methods to synthesize phase pure Sr- and Mg-doped LaGaO3 (LSGM), it is very interesting to achieve phase purity by changing the stoichiometry and additional co-doping. In this work, Pechini method is adopted to synthesize LSBGM (La0.8 Sr0.2− x Ba x Ga0.8 Mg0.2 O2.8 ) by co-doping of Ba 2+ and Sr 2+ at La-site, and Mg 2+ at Ga site. These multi-dopings eliminate the complexities in the synthesis and processing techniques, and desired single phase is achieved more easily. Tolerance factor, which is a measure of structural symmetry, increases from 0.9622 (in LSGM) to 0.9652 (in LSBGM). Moreover, an increase in 0.4% free volume occurred due to these multiple dopings at La-site. Enhancement in free volume and structural symmetry attribute to a higher ionic conductivity of LSBGM, which is also supported by XPS analysis. Ionic conductivity (0.046 S/cm at 600 °C) measured by impedance spectroscopic analysis is found to be >44% superior compared to the LSGM synthesized by similar/different processes. Additionally, a decrease in activation energy value suggests the lower vacancy–dopant interaction in LSBGM. Highlights: Compared to LSGM, LSBGM is synthesized more easily by Pechini method. By co-doping (Ba at La-site) in LSGM, structural symmetry and free volume increases. Ionic conductivity of LSBGM is enhanced >44% compared to LSGM. This is a novel way of phase stability and conductivity enhancement in LSGM.