Arrested α-hydride migration activates a phosphido ligand for C–H insertion. Issue 2 (13th December 2016)
- Record Type:
- Journal Article
- Title:
- Arrested α-hydride migration activates a phosphido ligand for C–H insertion. Issue 2 (13th December 2016)
- Main Title:
- Arrested α-hydride migration activates a phosphido ligand for C–H insertion
- Authors:
- Hickey, Anne K.
Muñoz, Salvador B.
Lutz, Sean A.
Pink, Maren
Chen, Chun-Hsing
Smith, Jeremy M. - Abstract:
- Abstract : Arrested α-hydride migration increases the nucleophilicity of the phosphorus atom in a phosphido ligand, facilitating [PR] group transfer reactivity. Abstract : Bulky tris(carbene)borate ligands provide access to high spin iron(ii ) phosphido complexes. The complex PhB(MesIm)3 FeP(H)Ph is thermally unstable, and [PPh] group insertion into a C–H bond of the supporting ligand is observed. An arrested α-hydride migration mechanism suggests increased nucleophilicity of the phosphorus atom facilitates [PPh] group transfer reactivity.
- Is Part Of:
- Chemical communications. Volume 53:Issue 2(2017)
- Journal:
- Chemical communications
- Issue:
- Volume 53:Issue 2(2017)
- Issue Display:
- Volume 53, Issue 2 (2016)
- Year:
- 2016
- Volume:
- 53
- Issue:
- 2
- Issue Sort Value:
- 2016-0053-0002-0000
- Page Start:
- 412
- Page End:
- 415
- Publication Date:
- 2016-12-13
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c6cc07864h ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 8990.xml