Surfactant‐Induced Preparation of Highly Dispersed Ni‐Nanoparticles Supported on Nanocrystalline ZrO2 for Chemoselective Reduction of Nitroarenes. Issue 4 (29th January 2018)

• Record Type: Journal Article
• Authors: Shukla, Astha; Singha, Rajib K.; Sengupta, Manideepa; Sasaki, Takehiko; Pendem, Chandrashekar; Bal, Rajaram
• Is Part Of: ChemistrySelect. Volume 3:Issue 4(2018)
• Page Start: 1129
• Page End: 1141
• Publication Date: 2018-01-29
• Subjects: Chemoselective reduction -- Heterogeneous catalysis -- Metal-support interaction -- Nickel nanoparticles -- Nitroarenes; Chemistry -- Periodicals; 540.5
• DOI: 10.1002/slct.201702631
• Languages: English
• ISSNs: 2365-6549

Abstract

Abstract: Metal‐support interaction plays crucial role in heterogeneous catalysis, stabilizing the active metal species during catalysis. We report here the successful preparation of highly dispersed nickel nanoparticles supported ZrO2 nanocrystals, which showed excellent performance toward catalytic reduction of nitroarenes to their corresponding amines, where metal‐support interaction plays the key role in enhancing the activity and stability of catalyst. The catalyst was synthesized by a single step hydrothermal method using CTAB (cetyltrimethyl ammonium bromide) as a structure‐ directing agent and PVP (Polyvinylpyrrolidone) as capping agent. Prepared catalyst was characterized by BET‐surface area, Inductively coupled plasma atomic emission spectroscopy (ICP‐AES), X‐ray diffraction (XRD), Scanning electron microscopy (SEM), Transmission electron microscopy (TEM), Temperature programmed reduction (TPR), X‐ray photoelectron spectroscopy (XPS), Fourier transform infra‐red (FT‐IR) spectroscopy, RAMAN spectroscopy, Thermogravimetric analysis (TGA‐DTA), UV‐vis spectroscopy and Extended X‐ray absorption fine structure (EXAFS) analysis. Results obtained from XRD and TPR analysis of 4.9% Ni‐ZrO2, support the presence of highly dispersed and subtle Ni (below 5 nm) nanoparticles supported on nanocrystalline ZrO2 . Prepared 4.9 wt% Ni‐ZrO2 catalyst showed 100% conversion of p ‐nitrophenol with >99% selectivity to p ‐aminophenol in aqueous medium at 60 °C, in presence of molecular H2 (1.0 MPa). Superior activity of 4.9% Ni‐ZrO2 was due to presence of very small (below 5 nm), uniformly distributed, highly dispersed nickel nanoparticle having good metal‐support interaction. Prepared 4.9% Ni‐ZrO2 catalyst was recycled up to eight successive runs without any significant loss in catalytic activity. Abstract : Nanocrystalline Ni‐ZrO2 as an efficient and cost‐effective heterogeneous catalyst for chemoselective reduction of nitroarenes to corresponding amines, under mild condition. Catalyst was prepared hydrothermally using CTAB as a structure‐directing agent, PVP as a capping agent and hydrazine as a reducing agent. Prepared catalyst enhances the activity towards chemoselective reduction of nitroarenes due to good metal support interaction.