Polyazines and Polyazomethines with Didodecylthiophene Units for Selective Dispersion of Semiconducting Single‐Walled Carbon Nanotubes. (17th August 2015)

• Record Type: Journal Article
• Authors: Gomulya, Widianta; Derenskyi, Vladimir; Kozma, Erika; Pasini, Mariacecilia; Loi, Maria Antonietta
• Is Part Of: Advanced functional materials. Volume 25:Number 36(2015)
• Page Start: 5858
• Page End: 5864
• Publication Date: 2015-08-17
• Subjects: field‐effect transistors -- polyazines -- polyazomethines -- single‐walled carbon nanotubes; Materials -- Periodicals; Chemical vapor deposition -- Periodicals; 620.11
• DOI: 10.1002/adfm.201502912
• Languages: English
• ISSNs: 1616-301X

Abstract

Abstract : Polymer wrapped single‐walled carbon nanotubes (SWNTs) have been demonstrated to be a very efficient technique to obtain high purity semiconducting SWNT solutions. However, the extraction yield of this technique is low compared to other techniques. Poly‐alkyl‐thiophenes have been reported to show higher extraction yield compare to polyfluorene derivatives. Here, the affinity for semiconducting SWNTs of two polymers with a backbone containing didodecylthiophene units interspersed with N atoms is reported. It is demonstrated that one of the polymers, namely, poly(2, 5‐dimethylidynenitrilo‐3, 4‐didodecylthienylene) (PAMDD), has very high semiconducting SWNT extraction yield compared to the poly(3, 4‐didodecylthienylene)azine (PAZDD). The dissimilar wrapping efficiency of these two polymers for semiconducting SWNTs is attributed to the interplay between the affinity for the nitrogen atoms of the highly polarizable walls of SWNTs and the mechanical flexibility of the polymer backbones. Photoluminescence (PL) measurements demonstrate the presence of metallic tubes and SWNT bundles in the sample selected with PAZDD and higher purity of SWNT‐PAMDD samples. The high purity of the semiconducting SWNTs selected by PAMDD is further demonstrated by the high performance of the solution‐processed field‐effect transistors (FETs) fabricated using a blade coating technique, which exhibit hole mobilities up to 33.3 cm 2 V −1 s −1 with on/off ratios of 10 6 . Abstract : A single‐wall carbon nanotube (SWNT) selective dispersion is obtained using polyazines and polyazomethines . Both polymers have didodecylthiophene units with direct nitrogen atoms in their backbone. The additional benzene ring in polyazomethines, which results in a stiffer polymer backbone, triggers different interaction with SWNTs. The high extraction yield of the SWNT dispersion by polyazomethines is essential for large‐scale separation of SWNT.