Effect of side groups on the properties of cationic polyaspartamides. (August 2017)

• Record Type: Journal Article
• Authors: Németh, Csaba; Szabó, Dóra; Gyarmati, Benjámin; Gerasimov, Alexander; Varfolomeev, Mikhail; Abdullin, Timur; László, Krisztina; Szilágyi, András
• Is Part Of: European polymer journal. Volume 93(2017)
• Page Start: 805
• Page End: 814
• Publication Date: 2017-08
• Subjects: Biopolymers -- Cationic polyaspartamide -- Thermal analysis -- Fluorescent marking -- Taste masking; Polymers -- Periodicals; Polymerization -- Periodicals; Polymères -- Périodiques; Polymérisation -- Périodiques; Polymerization; Polymers; Periodicals; Electronic journals; 547.705
• DOI: 10.1016/j.eurpolymj.2017.02.024
• Languages: English
• ISSNs: 0014-3057

Abstract

Graphical abstract: Highlights: Polyaspartamides with dialkylaminoalkyl and alkyl side groups were synthesized. The polymers have glass transition temperatures around 25 °C and are thermally stable. A correlation was established between the Tg and the polymer composition. Dissolution kinetics of the polymers was determined by fluorescent labeling. Abstract: Polyaspartamides with dialkylaminoalkyl and short chain alkyl side groups were synthesized and characterized in order to prepare polymer films. Their structure was confirmed by nuclear magnetic resonance ( 1 H NMR) and Fourier transform infrared (FTIR) spectroscopy and their thermal decomposition temperature (Td ) was determined by thermogravimetric analysis. The composition of the polymers was adjusted to obtain polyaspartamides with glass transition temperatures (Tg ) at around room temperature and the relationship between the structure and the properties was examined. The dissolution profile of polymer films made of polyaspartamides was measured with the help of fluorescent marking to show that dissolution rate of the films depends on the pH and can be controlled by the composition of the polymers.