In-depth investigation on the effect and role of cardanol in the compatibilization of PLA/ABS immiscible blends by reactive extrusion. (August 2017)

• Record Type: Journal Article
• Authors: Rigoussen, Alan; Verge, Pierre; Raquez, Jean-Marie; Habibi, Youssef; Dubois, Philippe
• Is Part Of: European polymer journal. Volume 93(2017)
• Page Start: 272
• Page End: 283
• Publication Date: 2017-08
• Subjects: PLA -- ABS -- Immiscible blend -- Cardanol -- Reactive extrusion -- Compatibilization; Polymers -- Periodicals; Polymerization -- Periodicals; Polymères -- Périodiques; Polymérisation -- Périodiques; Polymerization; Polymers; Periodicals; Electronic journals; 547.705
• DOI: 10.1016/j.eurpolymj.2017.06.004
• Languages: English
• ISSNs: 0014-3057

Abstract

Graphical abstract: Highlights: PLA/ABS immiscible blends were compatibilized using cardanol by reactive extrusion. Cardanol is grafting onto ABS through its phenolic ring during extrusion. Cardanol promotes the miscibility of PLA and ABS by decreasing ABS surface energy. With 5 wt% cardanol, the compatibilized blend exhibits one single Tα at 68.5 °C. Abstract: In this work, a sustainable approach was developed to melt-blend and enhance the compatibility of the immiscible blend of polylactide (PLA) and poly(acrylonitrile–butadiene–styrene) (ABS). Cardanol, a bio-based phenolic compound, was used as an interfacial (reactive) compatibilizer. The blending was conducted by a solvent-free reactive extrusion. The incorporation of cardanol resulted in an enhancement of the compatibility evidenced by the decrease of ABS nodules size within PLA from few micrometres to several tens of nanometres and the convergence of both polymers Tα around 68.5 °C. In-depth investigation evidenced that cardanol grafted onto ABS during the reactive extrusion via its phenolic ring, leading to a substantial plasticizing effect and a significant decrease of the surface energy of ABS, similar to those of PLA. This work paves the way to a multitude of new compatibilization strategies based on the reaction of phenolic compounds during the extrusion of PLA and ABS.