Doubly N‐Confused [36]Octaphyrin(1.1.1.1.1.1.1.1): Isomerization, Bis‐Metal Coordination, and Topological Chirality. (9th October 2017)
- Record Type:
- Journal Article
- Title:
- Doubly N‐Confused [36]Octaphyrin(1.1.1.1.1.1.1.1): Isomerization, Bis‐Metal Coordination, and Topological Chirality. (9th October 2017)
- Main Title:
- Doubly N‐Confused [36]Octaphyrin(1.1.1.1.1.1.1.1): Isomerization, Bis‐Metal Coordination, and Topological Chirality
- Authors:
- Mitsuno, Koki
Yoshino, Takafumi
Gupta, Iti
Mori, Shigeki
Karasawa, Satoru
Ishida, Masatoshi
Furuta, Hiroyuki - Abstract:
- Abstract: A novel [36]octaphyrin analogue embedding two N‐confused pyrrole units demonstrated unique prototropy‐coupled isomerization between the Figure‐of‐eight and dumbbell conformers. Upon bis‐metal coordination, fixation of fully π‐conjugated Figure‐of‐eight structures was achieved as referred from the X‐ray crystal structure. Chirogenesis of the helical enantiomers was proved by intense circular dichroism (CD) response in the near infrared (NIR) region.
- Is Part Of:
- Angewandte Chemie. Volume 129:Number 45(2017)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 129:Number 45(2017)
- Issue Display:
- Volume 129, Issue 45 (2017)
- Year:
- 2017
- Volume:
- 129
- Issue:
- 45
- Issue Sort Value:
- 2017-0129-0045-0000
- Page Start:
- 14440
- Page End:
- 14444
- Publication Date:
- 2017-10-09
- Subjects:
- Chiralität -- Helices -- Isomerisierungen -- Metallkoordination -- Octaphyrin
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201708253 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 8770.xml