Evaluating microstructure evolution in an SOFC electrode using digital volume correlation. Issue 12 (21st September 2018)

• Record Type: Journal Article
• Authors: Heenan, T. M. M.; Lu, X.; Finegan, D. P.; Robinson, J.; Iacoviello, F.; Bailey, J. J.; Brett, D. J. L.; Shearing, P. R.
• Is Part Of: Sustainable energy & fuels. Volume 2:Issue 12(2018)
• Page Start: 2625
• Page End: 2635
• Publication Date: 2018-09-21
• Subjects: Renewable energy sources -- Periodicals; Fuel cells -- Periodicals; Electric batteries -- Periodicals; Electrochemistry -- Periodicals; 660.297
• DOI: 10.1039/c8se00292d
• Languages: English
• ISSNs: 2398-4902

Abstract

Abstract : Degradation mechanisms that occur within solid oxide fuel cells (SOFC) during thermal cycling limit operational start-up times and cell lifetime, and must therefore be better understood and mitigated. Abstract : Degradation mechanisms within solid oxide fuel cells (SOFC) during thermal cycling limit operational start-up times and cell lifetime, and must therefore be better understood and mitigated. This work explores such mechanisms using digital volume correlation (DVC) techniques applied to lab-based X-ray tomograms where the microstructural evolution is evaluated during the operational cycling of a Ni–YSZ/YSZ cell. To emulate reduced start-up times, five tomograms were collected over four operational thermal cycles to 750 °C at various ramp-rates: 3, 10, 20 and 30 °C min −1 . Two key features are observed in the 3D strain profiles. Firstly, during low ramp-rates the material produces microscopic channels towards cluster-points. This is thought to be caused by the ceramic skeleton inhibiting the effects of sintering. Secondly, previously unseen macroscopic 'waves' developed after high-rate cycling, consisting of linear regions of compression and tension throughout the sample. These wave features decay away from a heterogeneous defect which is thought to be responsible for the non-uniform strain profile. This work demonstrates the first use of sub-micron DVC computations applied to an SOFC exposed to operationally relevant temperatures. These findings will assist in the development of new electrode materials from their fabrication to operation, ultimately supporting commercial viability of SOFCs.