Copper‐Catalyzed Oxidative Cross‐Coupling of P(O)‐OH Compounds with Aryl Boronic Acids. Issue 23 (16th August 2017)

• Record Type: Journal Article
• Authors: Xiong, Biquan; Cheng, Qing; Hu, Chenghong; Zhang, Pangliang; Liu, Yu; Tang, Kewen
• Is Part Of: ChemistrySelect. Volume 2:Issue 23(2017)
• Page Start: 6891
• Page End: 6894
• Publication Date: 2017-08-16
• Subjects: Copper catalysis -- Chan-Lam reaction -- P(O)-OH compounds -- Aryl boronic acids; Chemistry -- Periodicals; 540.5
• DOI: 10.1002/slct.201700716
• Languages: English
• ISSNs: 2365-6549

Abstract

Abstract: A novel copper‐catalyzed oxidative cross‐coupling reaction of P(O)‐OH compounds with aryl boronic acids is illustrated. It is a simple way to generate a broad spectrum of functionalized O ‐aryl phosphinates, phosphonates, and phosphates from basic starting materials with moderate to excellent yields. Furthermore, a plausible mechanism has been proposed for the reaction. Abstract : A novel copper‐catalyzed aerobic cross‐coupling of P(O)‐OH compounds with aryl boronic acids is illustrated. It is a simple way to generate a broad spectrum of functionalized O ‐aryl phosphinates, phosphonates, and phosphates from basic starting materials with moderate to excellent yields.