Exploiting electronic strategies to stabilize a planar tetracoordinate carbon in cyclic aromatic hydrocarbons. Issue 89 (26th October 2017)
- Record Type:
- Journal Article
- Title:
- Exploiting electronic strategies to stabilize a planar tetracoordinate carbon in cyclic aromatic hydrocarbons. Issue 89 (26th October 2017)
- Main Title:
- Exploiting electronic strategies to stabilize a planar tetracoordinate carbon in cyclic aromatic hydrocarbons
- Authors:
- Yañez, O.
Vásquez-Espinal, A.
Pino-Rios, R.
Ferraro, F.
Pan, S.
Osorio, E.
Merino, G.
Tiznado, W. - Abstract:
- Abstract : A new approach to stabilize compounds containing a planar tetracoordinate carbon (ptC), embedded in aromatic hydrocarbons, is presented herein. Abstract : A new approach to stabilize compounds containing a planar tetracoordinate carbon (ptC), embedded in aromatic hydrocarbons, is presented herein. This is achieved by using ligands that promote the formation of a 3c–2e σ-bond with the ptC under two conditions: without altering the sp 2 hybridization of the aromatic carbons; and containing empty orbitals perpendicular to the aromatic ring to participate in the aromatic π-electronic delocalization.
- Is Part Of:
- Chemical communications. Volume 53:Issue 89(2017)
- Journal:
- Chemical communications
- Issue:
- Volume 53:Issue 89(2017)
- Issue Display:
- Volume 53, Issue 89 (2017)
- Year:
- 2017
- Volume:
- 53
- Issue:
- 89
- Issue Sort Value:
- 2017-0053-0089-0000
- Page Start:
- 12112
- Page End:
- 12115
- Publication Date:
- 2017-10-26
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c7cc06248f ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 8712.xml