Frontispiece: A Highly Reactive Oxoiron(IV) Complex Supported by a Bioinspired N3O Macrocyclic Ligand. Issue 46 (8th November 2017)

• Record Type: Journal Article
• Authors: Monte Pérez, Inés; Engelmann, Xenia; Lee, Yong‐Min; Yoo, Mi; Kumaran, Elumalai; Farquhar, Erik R.; Bill, Eckhard; England, Jason; Nam, Wonwoo; Swart, Marcel; Ray, Kallol
• Is Part Of: Angewandte Chemie international edition. Volume 56:Issue 46(2017)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2017-11-08
• Subjects: hydrogen atom transfer -- O ligands -- oxoiron(IV) complexes -- oxygen atom transfer -- spin state; Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201784661
• Languages: English
• ISSNs: 1433-7851

Abstract

Abstract : Iron Oxo Complexes In their Communication onpage 14384 ff., W. Nam, M. Swart, K. Ray, et al. show that the oxoiron(IV) center in [Fe IV (O)(TMCO)(OTf)] + (bottom right) with an N3 O environment is significantly more reactive than that in [Fe IV (O)(TMC)(CH3 CN)] 2+ (top left) with an N4 environment.