Wigner‐Smith delay times and the non‐Hermitian Hamiltonian for the HOCl molecule. Issue 2 (1st June 2012)

• Record Type: Journal Article
• Authors: Barr, A.M.; Reichl, L.E.
• Other Names: Bird J. sponsoringEditor.; Kaiser R. sponsoringEditor.; Rotter I. sponsoringEditor.; Wunner G. sponsoringEditor.
• Is Part Of: Fortschritte der Physik. Volume 61:Issue 2/3(2013)
• Page Start: 59
• Page End: 65
• Publication Date: 2012-06-01
• Subjects: Non‐Hermitian Hamiltonian -- Wigner‐Smith delay times -- scattering of HOCl system.; Physics -- Periodicals; 530.05
• DOI: 10.1002/prop.201200045
• Languages: English
• ISSNs: 0015-8208

Abstract

Abstract: We construct the scattering matrix for a two‐dimensional model of a Cl atom scattering from an OH dimer. We show that the scattering matrix can be written in terms of a non‐Hermitian Hamiltonian whose complex energy eigenvalues can be used to compute Wigner‐Smith delay times for the Cl‐OH scattering process. We compute the delay times for a range of energies, and show that the scattering states with the longest delay times are strongly influenced by unstable periodic orbits in the classical dynamics.