A high performance P(VDF-TrFE) nanogenerator with self-connected and vertically integrated fibers by patterned EHD pulling. Issue 27 (18th May 2015) - Chen, Xiaoliang
Abstract : A patterned electrohydrodynamic pulling technology was first proposed to fabricate a new self-connected, vertically integrated nanogenerator with a well-bridged electrode pair. Abstract : Piezoelectricity based energy harvesting from mechanical vibrations has attracted extensive attention for its potential application in powering wireless mobile electronics recently. Here, a patterned electrohydrodynamic (EHD) pulling technology was proposed to fabricate a new self-connected, piezoelectric fiber array vertically integrated P(VDF-TrFE) nanogenerator, with a molecular poling orientation fully aligned to the principal excitation for maximized conversion and a well-bridged electrode pair for efficient charge collection. The nanogenerator is fabricated in a novel way by applying a voltage across an electrode pair sandwiching an air gap and an array of shallow micropillars, during which the EHD force tends to pull the micropillars upward, generating a microfiber array finally in robust contact with the upper electrode. Such a thermoplastic and EHD deformation of the microfibers, featured simultaneously by an electric field and by a microfiber elongation dominantly vertical to the electrode, leads to a poling orientation of P(VDF-TrFE) well coincident with the principal strain for the generator excited by a force normal to the electrodes. The as-prepared piezoelectric device exhibits an enhanced output voltage up to 4.0 V and a current of 2.6 μA, therefore the piezoelectric voltage was enhanced to 5.4 times that from the bulk film. Under periodic mechanical impact, electric signals are repeatedly generated from the device and used to power a seven-segment indicator, RBGY colored light-emitting diodes, and a large-scale liquid crystal display screen. These results not only provide a tool for fabricating 3D piezoelectric polymers but offer a new type of self-connected nanogenerator for the next generation of self-powered electronics.