Activation of Remote meta‐C−H Bonds in Arenes with Tethered Alcohols: A Salicylonitrile Template. (23rd August 2017)
- Record Type:
- Journal Article
- Title:
- Activation of Remote meta‐C−H Bonds in Arenes with Tethered Alcohols: A Salicylonitrile Template. (23rd August 2017)
- Main Title:
- Activation of Remote meta‐C−H Bonds in Arenes with Tethered Alcohols: A Salicylonitrile Template
- Authors:
- Zhang, Lanlan
Zhao, Chaoyue
Liu, Yang
Xu, Jiancong
Xu, Xiufang
Jin, Zhong - Abstract:
- Abstract: Palladium‐catalyzed activation of remote meta ‐C−H bonds in arenes containing tethered alcohols was achieved with high regioselectivity by using a nitrile template. Computational studies on the macrocyclic transition state of the regioselectivity‐determining C−H activation steps revealed that both the C‐N‐Ag angles and gauche comformations of phenyl ether play an extremely important role in the meta selectivity.
- Is Part Of:
- Angewandte Chemie. Volume 129:Number 40(2017)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 129:Number 40(2017)
- Issue Display:
- Volume 129, Issue 40 (2017)
- Year:
- 2017
- Volume:
- 129
- Issue:
- 40
- Issue Sort Value:
- 2017-0129-0040-0000
- Page Start:
- 12413
- Page End:
- 12417
- Publication Date:
- 2017-08-23
- Subjects:
- Arene -- C-H-Aktivierung -- Dichtefunktionalrechnungen -- Palladium -- Regioselektivität
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201705495 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 8637.xml