Molybdenum disulfide nanosheet embedded three-dimensional vertically aligned carbon nanotube arrays for extremely-excellent cycling stability lithium-ion anodes. Issue 83 (25th August 2016)

• Record Type: Journal Article
• Authors: Fan, Haining; Chen, Xiaohua; Tang, Qunli; Chen, Shanliang; Fan, Binbin; Hu, Aiping; Zhang, Shiying; Li, Yanghua
• Is Part Of: RSC advances. Volume 6:Issue 83(2016)
• Page Start: 80320
• Page End: 80327
• Publication Date: 2016-08-25
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1039/c6ra17042k
• Languages: English
• ISSNs: 2046-2069

Abstract

Abstract : Molybdenum disulfide (MoS2 ) nanosheets embedded in 3D vertically aligned carbon nanotube arrays (VACNTs) have been fabricated via a simple nebulization-assisted hydrothermal method and exhibited extremely-excellent cycling stability. Abstract : Molybdenum disulfide (MoS2 ) nanosheets embedded in three-dimensional (3D) vertically aligned carbon nanotube arrays (VACNTs) have been fabricated via a simple nebulization-assisted hydrothermal method. The MoS2 /VACNTs possess a highly ordered and uniformly oriented 3D structure with MoS2 nanosheets adhering strictly to the surface of VACNTs. When evaluated as lithium-ion anode materials, so-obtained MoS2 /VACNTs composites containing 52 wt% MoS2 exhibit superb electrochemical performances, including high capacity (1078 mA h g −1 at 100 mA g −1 after 1st cycle), good rate capability (789 mA h g −1 at 2000 mA g −1 after 20 cycles), and extremely-excellent cycling stability, for the MoS2 /VACNTs electrode can still deliver a discharge capacity of 512 mA h g −1 after 1000 cycles at 5000 mA g −1, compared with pristine MoS2 (negligible discharge capacity at the 70th cycle). Such high electrical properties can mainly be attributed to the unique well-directed pore-morphology which provides low-resistant shortest diffusion pathways upon the high-conductive VACNTs to accelerate ion/electron movement. Moreover, the elastic spare-space inside/outside VACNTs as a buffer factor effectively restrains large volumetric change from MoS2 during the charge/discharge process. It can be determined that such a structure is attractive to achieve extremely-excellent cycling stability lithium-ion anodes.