Encapsulation and Dynamic Behavior of Methanol and Formaldehyde inside Open‐Cage C60 Derivatives. Issue 10 (31st January 2017)

• Record Type: Journal Article
• Authors: Futagoishi, Tsukasa; Murata, Michihisa; Wakamiya, Atsushi; Murata, Yasujiro
• Is Part Of: Angewandte Chemie international edition. Volume 56:Issue 10(2017)
• Page Start: 2758
• Page End: 2762
• Publication Date: 2017-01-31
• Subjects: carbon nanomaterials -- fullerenes -- host–guest chemistry -- open-cage C60 -- X-ray crystallography; Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201611903
• Languages: English
• ISSNs: 1433-7851

Abstract

Abstract: Methanol (CH3 OH) and formaldehyde (H2 CO) molecules were inserted into an open‐cage C60 derivative with a large opening, under high‐pressure and high‐temperature conditions in solution. Isolation of their molecular complexes in pure form was achieved by the use of recycling HPLC with Buckyprep columns. 1 H NMR spectroscopy, single‐crystal X‐ray diffraction studies, and DFT calculations revealed the orientation of the encapsulated CH3 OH and H2 CO, both in solution and in the solid state, and the results show that the CH3 group of the CH3 OH and the carbonyl group of the H2 CO point to the bottom of the cages. Furthermore, the dynamic behavior of the CH3 OH and H2 CO were studied at the molecular level. Abstract : One and only : Molecular complexes encapsulating CH3 OH and H2 CO inside open‐cage C60 derivatives were synthesized. The orientations of the encapsulated species in solution and in the solid state were revealed by NMR analysis, single‐crystal X‐ray analysis, and DFT calculations. Each species shows only one orientation: the CH3 group of the CH3 OH sits on the curve of the carbon cage, whereas the CH2 group of the H2 CO is directed toward the opening.