Frontispiece: Entropy‐Driven 1, 2‐Type Friedel–Crafts Reaction of Phenols with N‐tert‐Butoxycarbonyl Aldimines. Issue 51 (4th December 2015)

• Record Type: Journal Article
• Authors: Kato, Masaru; Hirao, Shogo; Nakano, Katsuhiro; Sato, Makoto; Yamanaka, Masahiro; Sohtome, Yoshihiro; Nagasawa, Kazuo
• Is Part Of: Chemistry. Volume 21:Issue 51(2015)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2015-12-04
• Subjects: entropy -- Friedel–Crafts reactions -- organocatalysis -- phenols -- transition states; Chemistry -- Periodicals; 540
• DOI: 10.1002/chem.201585162
• Languages: English
• ISSNs: 0947-6539

Abstract

Abstract : Friedel–Crafts Reaction Efforts to identify factors that contribute to the attainment of a large magnitude of ΔΔ S ≠ in the Friedel–Crafts reaction and DFT calculations in the transition‐state model shines a light on an area of emerging opportunity to link the ΔΔ S ≠ effect and the molecular structure of the conformationally flexible organocatalysts. For more details, see the Full Paper by K. Nagasawa et al. onpage 18606 ff.