Structural optimization of graphite for high-performance fluorinated ethylene–propylene composites as bipolar plates. (29th November 2018)

• Record Type: Journal Article
• Authors: Lee, Moon Hee; Kim, Ho Young; Oh, Seong Moon; Kim, Byung Choon; Bang, Daesuk; Han, Joong Tark; Woo, Jong Seok
• Is Part Of: International journal of hydrogen energy. Volume 43:Number 48(2018)
• Page Start: 21918
• Page End: 21927
• Publication Date: 2018-11-29
• Subjects: Graphite -- Fluorinated ethylene–propylene -- Bipolar plate -- Particle size -- Twin-screw extruder -- Compression molding; BP bipolar plate -- EMI electromagnetic interference -- FEP fluorinated ethylene–propylene -- FE-SEM field-emission scanning electron microscope -- HT high temperature -- HT-BP high-temperature bipolar plate -- PAFC phosphoric acid fuel cell -- PEMFC proton-exchange membrane fuel cell -- PFA polyfluoroalkoxyethylene -- PSA particle-size analyzer -- PTFE poly(tetrafluoroethylene) -- UTM universal testing machine; Hydrogen as fuel -- Periodicals; Hydrogène (Combustible) -- Périodiques; Hydrogen as fuel; Periodicals; 665.81
• DOI: 10.1016/j.ijhydene.2018.09.104
• Languages: English
• ISSNs: 0360-3199

Abstract

Abstract: This paper presents a novel method of structural optimization by using graphite particles ranging in size from 35 to 500 μm to fabricate conductive fluorinated ethylene–propylene composites for high-temperature bipolar plates. To investigate the effects of dispersion and packing density, the large graphite particles were decorated with fluorinated ethylene–propylene powders by ball milling, and the master batch of well-dispersed small graphite particles and polymer master batch was mixed with large graphite particles. The resulting fluorinated ethylene–propylene/graphite composite bipolar plates, which contained 65 wt% graphite, exhibited high electrical conductivity of 550 S cm −1 . In particular, by modulating the electrical transportation paths between the large graphite particles with the well-dispersed fluorinated ethylene–propylene/graphite master batch, the orientation and dispersion of the graphite particles in the matrix resulted in enhanced electrical conductivity and mechanical properties. The preparation of structurally optimized fluorinated ethylene–propylene/graphite composite bipolar plates with well-dispersed graphite particles of different sizes provides a robust and scalable strategy for realizing high-performance and large-area bipolar plates. Graphical abstract: Highlights: FEP/graphite composites were prepared by melt-processing from a master batch. Graphite particles of different sizes were dispersed in the master batch. FEP/graphite composite bipolar plates (BPs) were prepared by compression molding. Structurally optimized BPs had high electrical conductivity and mechanical properties. The composites represent a robust and scalable strategy for large-area BPs.