A novel catalyst system for the synthesis of N, N′-Methylenebisacrylamide from acrylamide. Issue 1 (1st January 2017)

• Record Type: Journal Article
• Authors: Avşar, Abdullah; Gökbulut, Yener; Ay, Burak; Serin, Selahattin
• Is Part Of: Designed monomers and polymers. Volume 20:Issue 1(2017)
• Page Start: 434
• Page End: 440
• Publication Date: 2017-01-01
• Subjects: N, N′-Methylenebisacrylamide -- catalyst -- monomer synthesis -- Cu(II) complex; Monomers -- Periodicals; Polymers -- Periodicals; Macromolecules -- Periodicals; Polymerization -- Periodicals; 547.7005
• DOI: 10.1080/15685551.2017.1332138
• Languages: English
• ISSNs: 1385-772X

Abstract

Abstract: N, N′-Methylenebisacrylamide (MBAA), which is an important raw material in a widely industrial area, was synthesized using convenient catalysts. The synthesized monomer was fully characterized by the elemental analysis, fourier transform infrared (FT-IR) spectroscopy, thermogravimetric analysis (TGA), 1 H-NMR, 13 C-NMR, GC/MS, and high performance liquid chromatography (HPLC) analysis. Six different homogeneous and heterogeneous catalysts were used to obtain maximum monomer yield. The MBAA was obtained with 95% yield by using Cu(II) catalyst containing carboxylate groups ligands.