Oxidation of CO on Pd(1 0 0): on the structural evolution of the PdO layer during the self sustained oscillation regime. (3rd April 2017)

• Record Type: Journal Article
• Authors: Onderwaater, Willem G.; Balmes, Olivier; Roobol, Sander B.; Van Spronsen, Matthijs; Drnec, Jakub; Carla, Francesco; Felici, Roberto; Frenken, Joost W. M.
• Is Part Of: Catalysis, structure & reactivity. Volume 3:Number 1/2(2017)
• Page Start: 89
• Page End: 94
• Publication Date: 2017-04-03
• Subjects: Heterogeneous catalysis -- self-sustained reaction oscillations -- CO oxidation -- Pd(1 0 0) -- surface X-ray diffraction; Catalysts -- Periodicals; Catalysis -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; 660.2995
• DOI: 10.1080/2055074X.2017.1280641
• Languages: English
• ISSNs: 2055-074X

Abstract

Abstract: Under particular temperature and gas conditions the reactivity of the Pd(1 0 0) surface toward CO oxidation exhibits oscillatory behaviour. Here we examine the surface structure of this model catalyst and show that the periodic pattern is more complex than previously reported and that superimposed on the overall oscillation much faster structural variations are present. By examining the structure of the sample surface at high temporal resolution we conclude that the structure of the oxide layer present at the surface evolves continuously toward a more disordered phase in agreement with the Mars-Van Krevelen reaction mechanism. Abstract :