Vibrationally resolved B 1s photoionization cross section of BF3. (August 2015)

• Record Type: Journal Article
• Authors: Ayuso, D; Kimura, M; Kooser, K; Patanen, M; Plesiat, E; Argenti, L; Mondal, S; Travnikova, O; Sakai, K; Palacios, A; Kukk, E; Decleva, P; Ueda, K; Martín, F; Miron, C
• Is Part Of: Journal of physics. Number 635(2015)
• Publication Date: 2015-08
• Subjects: Physics -- Congresses; 530.5
• DOI: 10.1088/1742-6596/635/11/112134
• Languages: English
• ISSNs: 1742-6588

Abstract

Synopsis: We present a study of the vibrationally resolved B 1s photoionization cross section of the BF3 molecule. A combination of high-resolution photoelectron spectroscopy measurements and of state-of-the-art calculations shows the evolution of the photon energy dependence of the cross section from a complete trapping of the photoelectron wave (low energies) to oscillations due to intramolecular scattering. These diffraction patterns allow to access structural information of both the neutral molecule and the core -hole species generated upon photoabsoption.