Fracture and fatigue behaviour of epoxy nanocomposites containing 1-D and 2-D nanoscale carbon fillers. (November 2018)

• Record Type: Journal Article
• Authors: Ladani, Raj B.; Bhasin, Mukesh; Wu, Shuying; Ravindran, Anil R.; Ghorbani, Kamran; Zhang, Jin; Kinloch, Anthony J.; Mouritz, Adrian P.; Wang, Chun H.
• Is Part Of: Engineering fracture mechanics. Volume 203(2018)
• Page Start: 102
• Page End: 114
• Publication Date: 2018-11
• Subjects: Epoxies -- Fatigue behaviour -- Fracture energy -- Modelling -- Nanocomposites; Fracture mechanics -- Periodicals; Rupture, Mécanique de la -- Périodiques; Fracture mechanics; Periodicals; 620.112605
• DOI: 10.1016/j.engfracmech.2018.04.033
• Languages: English
• ISSNs: 0013-7944

Abstract

Highlights: Shows improvements in an epoxy by using CNF or GNP or CNF/GNP hybrid nanofillers. Fracture and fatigue properties improved. Toughening mechanisms have been identified. Successful model developed. Abstract: The present paper describes improvements in the fracture resistance of epoxy polymers due to the addition of either (a) one-dimensional (1-D) carbon nanofibres (CNFs), or (b) two-dimensional (2-D) graphene nanoplatelets (GNPs), or (c) hybrid combinations of these carbon nanofillers (i.e. using both CNFs and GNPs). The effects of the dimensional shape and concentration (i.e. 0.0, 0.5, 1.0, 1.5 and 2.0 wt%) of the nanoscale carbon fillers are considered. The addition of CNFs, GNPs or hybrid combinations of CNFs and GNPs increases greatly the quasi-static fracture energy, GIc, of the epoxy due to these nanofillers inducing multiple intrinsic (e.g. interfacial debonding and void growth) and extrinsic (e.g. pull-out and bridging) toughening mechanisms. A mechanistic model is presented to quantify the contributions from the different toughening mechanisms induced by the CNF and the GNP fillers which result in the improvements observed in the fracture energy. The resistance of the epoxy, modified with either the GNPs or the CNFs, to cyclic-fatigue loading is also increased by the presence of the carbon nanofillers.