Tunable Stimuli‐Responsive Color‐Change Properties of Layered Organic Composites. (19th September 2018)

• Record Type: Journal Article
• Authors: Takeuchi, Machi; Gnanasekaran, Karthikeyan; Friedrich, Heiner; Imai, Hiroaki; Sommerdijk, Nico A. J. M.; Oaki, Yuya
• Is Part Of: Advanced functional materials. Volume 28:Number 45(2018)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2018-09-19
• Subjects: in situ analyses -- intercalation -- layered materials -- organic–inorganic composites -- stimuli‐responsive materials; Materials -- Periodicals; Chemical vapor deposition -- Periodicals; 620.11
• DOI: 10.1002/adfm.201804906
• Languages: English
• ISSNs: 1616-301X

Abstract

Abstract: Stimuli‐responsive properties of soft materials originate from dynamic structure changes. Layered polydiacetylene (PDA) shows color‐change properties with the application of external stimuli, such as thermal and mechanical stresses. Layered organic materials possessing intercalation capabilities and dynamic properties have potentials for tuning their structures and properties by the intercalated guests. A variety of sensing and imaging devices can be developed by control of the stimuli responsivity. Here, the key structures, processes, and mechanisms for tuning the stimuli‐responsive color‐change properties of layered PDA are studied by in situ analyses with heating and cooling. The in situ analyses indicate that heating initiates thermal motion of the alkyl side chains of the PDA main chain in the host layers around 60 °C, regardless of the type of intercalated guests. Further heating induces torsion of the PDA main chain leading to color changes at different temperatures, depending on the types of the intercalated guest. Then, the layered structure is irreversibly deformed with lowering the crystallinity. The results indicate that the stimuli‐responsive color‐change properties are controlled by the rigidity of the layered structures consisting of the host layers and guests. The control strategy based on rigidity tuning can be applied to a variety of soft materials with stimuli responsivity. Abstract : The tunable soft and rigid nature of organic layered structures with intercalation control the stimuli‐responsive color‐change properties of layered polydiacetylene, such as color, responsivity, and reversibility. In situ analyses reveal the relationship between the layered structure and stimuli‐responsive color‐change properties. The interlayer guests determine the rigidity of the organic layered materials and their properties.