CoSe2 nanoparticles grown on carbon nanofibers derived from bacterial cellulose as an efficient electrocatalyst for hydrogen evolution reaction. (8th November 2018)

• Record Type: Journal Article
• Authors: Wei, Licheng; Luo, Jiaxian; Jiang, Lijuan; Qiu, Lijun; Zhang, Jinming; Zhang, Dawei; Xu, Peiman; Yuan, Dingsheng
• Is Part Of: International journal of hydrogen energy. Volume 43:Number 45(2018)
• Page Start: 20704
• Page End: 20711
• Publication Date: 2018-11-08
• Subjects: Hydrogen evolution reaction -- CNFs/CoSe2 -- 3D network structure -- Active sites -- Cycling stability; Hydrogen as fuel -- Periodicals; Hydrogène (Combustible) -- Périodiques; Hydrogen as fuel; Periodicals; 665.81
• DOI: 10.1016/j.ijhydene.2018.09.151
• Languages: English
• ISSNs: 0360-3199

Abstract

Abstract: Exploration of high-efficiency and inexpensive Pt-free electrochemical catalysts for hydrogen evolution reaction (HER) is highly significative for carbon dioxide free energy conversion systems. In this work, we described the development of CoSe2 nanoparticles grown on the carbon nanofibers (CNFs) derived from bacterial cellulose (CNFs/CoSe2 ) through a facile one-step hydrothermal preparation, which not only showed a three-dimensional (3D) porous network structure, but also possessed large surface area. This rationally designed architecture realizes the uniform distribution of CoSe2 nanoparticles to provide with fully exposed active edges and the unique conductive interwoven carbon nanofibers facilitates the charge transportation in HER process, thus leading to remarkable HER activity. As expected, the CNFs/CoSe2 shows a low onset overpotential of −85 mV, low overpotential (η10 = 119 mV) for reaching a current density of −10 mA cm − 2 and smaller Tafel slope of 54 mV dec −1 as well as good cycling stability in acidic electrolyte. Highlights: CoSe2 nanoparticles grown on the carbon nanofibers (CNFs/CoSe2 ) have successfully synthesized. The CNFs/CoSe2 possesses 3D porous network structure and large specific surface area. The CNFs/CoSe2 not only exposes more active sites but also facilitates charge transportation. The CNFs/CoSe2 exhibits a remarkable HER activity.