Acetamidoarenediazonium Salts: Opportunities for Multiple Arene Functionali­zation. Issue 26 (31st July 2015)

• Record Type: Journal Article
• Authors: Schmidt, Bernd; Elizarov, Nelli; Riemer, Nastja; Hölter, Frank
• Is Part Of: European journal of organic chemistry. Issue 26(2015)
• Page Start: 5826
• Page End: 5841
• Publication Date: 2015-07-31
• Subjects: Arenes -- Amides -- C–C cou­pling -- Cross‐coupling -- Palladium; Chemistry, Organic -- Periodicals; Organic compounds -- Synthesis -- Periodicals; Bioorganic chemistry -- Periodicals; Chemistry, Physical organic -- Periodicals; 547
• DOI: 10.1002/ejoc.201500795
• Languages: English
• ISSNs: 1434-193X

Abstract

Abstract: Unlike their ortho counterparts, meta ‐ and para ‐acetamidoanilines can be converted into the corresponding acetamidoarenediazonium salts. These offer various opportunities for multiple Pd‐catalyzed arene functionalization reactions, such as Matsuda–Heck‐, Suzuki–Miyaura‐ or Fujiwara–Moritani couplings. Abstract : Acetamidoarenediazonium salts, accessible from simple acetamidoanilines, are starting points for multiple Pd‐catalyzed arene functionalization reactions.