A triplet biradical with double bidentate sites based on tert-butyl pyridyl nitroxide as a candidate for strong ferromagnetic couplers. (15th October 2018)
- Record Type:
- Journal Article
- Title:
- A triplet biradical with double bidentate sites based on tert-butyl pyridyl nitroxide as a candidate for strong ferromagnetic couplers. (15th October 2018)
- Main Title:
- A triplet biradical with double bidentate sites based on tert-butyl pyridyl nitroxide as a candidate for strong ferromagnetic couplers
- Authors:
- Okazawa, Atsushi
Terakado, Yutaro
Ishida, Takayuki
Kojima, Norimichi - Abstract:
- Abstract : A new triplet biradical having two chelatable nitroxide sites and a strong intramolecular ferromagnetic coupling through a " meta – para " bipyridyl linker. Abstract : We synthesised a new biradical, 34bpybNO, having two chelating radical sites and demonstrated its crystal structure and ground triplet nature. Frozen-solution magnetic measurement and electron spin resonance results revealed a strong intramolecular ferromagnetic coupling reaching 2 J / k B = ∼+170 K, which is supported by density functional theory calculations.
- Is Part Of:
- New journal of chemistry. Volume 42:Number 22(2018)
- Journal:
- New journal of chemistry
- Issue:
- Volume 42:Number 22(2018)
- Issue Display:
- Volume 42, Issue 22 (2018)
- Year:
- 2018
- Volume:
- 42
- Issue:
- 22
- Issue Sort Value:
- 2018-0042-0022-0000
- Page Start:
- 17874
- Page End:
- 17878
- Publication Date:
- 2018-10-15
- Subjects:
- Chemistry -- Periodicals
Chimie -- Périodiques
540 - Journal URLs:
- http://www.rsc.org/ ↗
http://www.rsc.org/is/journals/current/newjchem/njc.htm ↗ - DOI:
- 10.1039/c8nj04180f ↗
- Languages:
- English
- ISSNs:
- 1144-0546
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 6084.319900
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 8443.xml