Self-assembly of graphitic carbon nitride nanosheets–carbon nanotube composite for electrochemical simultaneous determination of catechol and hydroquinone. (10th September 2015)

• Record Type: Journal Article
• Authors: Zhang, Hanqiang; Huang, Yihong; Hu, Shirong; Huang, Qitong; Wei, Chan; Zhang, Wuxiang; Yang, Weize; Dong, Peihui; Hao, Aiyou
• Is Part Of: Electrochimica acta. Volume 176(2015)
• Page Start: 28
• Page End: 35
• Publication Date: 2015-09-10
• Subjects: Graphitic carbon nitride nanosheets -- Carbon nanotube -- Electrochemical determination -- Catechol -- Hydroquinone; Electrochemistry -- Periodicals; Electrochemistry, Industrial -- Periodicals; 541.37
• DOI: 10.1016/j.electacta.2015.06.119
• Languages: English
• ISSNs: 0013-4686

Abstract

Graphical abstract: Schematic diagram of hydrothermal synthesis graphitic carbon nitride nanosheets-carbon nanotube composite and theirs application for electrochemical sensing catechol and hydroquinone. Highlights: Self-assembly of graphitic carbon nitride nanosheets-carbon nanotube composite. CNNS-CNT show more stronger conductivity than CNNS and CNT. CNNS-CNT has been performed for detection of catechol and hydroquinone. The probe was applied to detect practical samples with satisfactory results. Abstract: In this paper, three-dimensional (3D) graphitic carbon nitride nanosheets-carbon nanotube (CNNS-CNT) composite was synthesized via hydrothermal reaction of 2D CNNS and 1D CNT-COOH by π-π stacking and electrostatic interactions. This CNNS-CNT composite was characterized by transmission electron microscope, scanning electron microscope, x-ray diffraction and fourier-transform infrared. In addition, the CNNS-CNT composite displayed excellent conductivity comparing with CNNS and CNT-COOH monomer. This composite was applied for electrochemical simultaneous determination of catechol (CC) and hydroquinone (HQ) with good sensitivity, wide linear range and low detection limit. In addition, this CNNS-CNT composite modified electrode was also applied to detect practical samples with satisfactory results.