Cellulose nanocrystals prepared via formic acid hydrolysis followed by TEMPO-mediated oxidation. (20th November 2015)

• Record Type: Journal Article
• Authors: Li, Bin; Xu, Wenyang; Kronlund, Dennis; Määttänen, Anni; Liu, Jun; Smått, Jan-Henrik; Peltonen, Jouko; Willför, Stefan; Mu, Xindong; Xu, Chunlin
• Is Part Of: Carbohydrate polymers. Volume 133(2015)
• Page Start: 605
• Page End: 612
• Publication Date: 2015-11-20
• Subjects: Cellulose nanocrystals -- Formic acid -- TEMPO oxidation -- Characterization -- Rheology; Polysaccharides -- Periodicals; Polysaccharides -- Periodicals; Polysaccharides -- Périodiques; Electronic journals; 547.78
• DOI: 10.1016/j.carbpol.2015.07.033
• Languages: English
• ISSNs: 0144-8617

Abstract

Highlights: CNCs could be isolated by formic acid (FA) hydrolysis. FA could be recovered and reused in the production of CNCs. CNCs produced by FA could be modified by TEMPO-mediated oxidation. The modified CNCs had higher surface charge and better redispersibility in water. The modified CNCs could be more effective when used as rheology modifier. Abstract: Cellulose nanocrystals (CNCs) as a renewable and biodegradable nanomaterial have wide application value. In this work, CNCs were extracted from bleached chemical pulp using two stages of isolation ( i.e. formic acid (FA) hydrolysis and 2, 2, 6, 6-tetramethyl-piperidine-1-oxyl (TEMPO) mediated oxidation) under mild conditions. In the first stage, FA was used to remove hemicellulose, swell cellulose fibers, and release CNCs. The FA could be readily recovered and reused. In the second stage, the CNCs isolated by FA were further modified by TEMPO-mediated oxidation to increase the surface charge of CNCs. It was found that the modified CNCs with more ordered crystal structure and higher surface charge had better redispersibility and higher viscosity in aqueous phase. Therefore, the modified CNCs could be more effective when used as rheology modifier in the fields of water based coating, paint, food etc.