Structural and functional modifications induced by X-ray nanopatterning in Bi-2212 single crystals. Issue 42 (3rd October 2018)

• Record Type: Journal Article
• Authors: Bonino, Valentina; Agostino, Angelo; Prestipino, Carmelo; Hernandez, Olivier; Fretto, Matteo; Mino, Lorenzo; Truccato, Marco
• Is Part Of: CrystEngComm. Volume 20:Issue 42(2018)
• Page Start: 6667
• Page End: 6676
• Publication Date: 2018-10-03
• Subjects: Crystals -- Periodicals; Crystal growth -- Periodicals; Crystallography -- Periodicals; Cristaux -- Périodiques; Cristaux -- Croissance -- Périodiques; Cristallographie -- Périodiques; 548
• DOI: 10.1039/c8ce01183d
• Languages: English
• ISSNs: 1466-8033

Abstract

Abstract : X-ray nanopatterning induces both mosaicity increase and oxygen depletion in the high- T c superconductor Bi2 Sr2 CaCu2 O8+ δ . Abstract : We have investigated the modifications induced in the high- T c superconductor Bi2 Sr2 CaCu2 O8+ δ (Bi-2212) by X-ray nanopatterning, which is an innovative, photoresist-free, direct-writing approach recently used to fabricate proof-of-concept electrical devices [Truccato et al., Nano Lett., 2016, 16, 1669]. By means of combined synchrotron microdiffraction and electrical transport measurements carried out on the same Bi-2212 microcrystal, we show that hard X-ray irradiation with fluences of the order of 10 12 J m −2, corresponding to doses of the order of 10 13 Gy, induces crystal fragmentation into multiple subdomains and decreases the carrier density of the system. We ascertain that the synergistic action of grain boundaries and of oxygen removal from the material dramatically changes the properties of Bi-2212 both in the normal and in the superconducting state. This special feature of X-ray nanopatterning introduces an opportunity that could be exploited to finely tune material structural defects according to the desired properties.