Ultralong needle-like N-doped Co(OH)F on carbon fiber paper with abundant oxygen vacancies as an efficient oxygen evolution reaction catalyst. (18th September 2018)

• Record Type: Journal Article
• Authors: Lv, Jiaqi; Yang, Xiaoxuan; Zang, Hong-Ying; Wang, Yong-Hui; Li, Yang-Guang
• Is Part Of: Materials chemistry frontiers. Volume 2:Number 11(2018)
• Page Start: 2045
• Page End: 2053
• Publication Date: 2018-09-18
• Subjects: Materials science -- Periodicals; Chemistry -- Periodicals; 540
• DOI: 10.1039/c8qm00405f
• Languages: English
• ISSNs: 2052-1529

Abstract

Abstract : The 3D needle-like N-doped Co(OH)F on carbon fiber paper rich in oxygen vacancies synthesized by hydrothermal method has an efficient oxygen evolution performance. Abstract : Although significant efforts have been devoted to designing efficient electrocatalysts for the oxygen evolution reaction, further progress is still needed regarding modulating the microstructures of electrocatalysts to further improve catalytic activity. Herein, utilizing ionic compound NaF and heteroatom-N-rich urea as morphology directing reagents, ultralong needle-like N-doped Co(OH)F supported on carbon fiber paper has been synthesized through a one-step hydrothermal method. Specifically, the hydrothermal kettle provides a stable environment for the formation of ultra-long needle-like structures. Meanwhile, with the addition of halogen anion F − and heteroatom N, a wealth of oxygen vacancies are obtained, and the OER activity is enhanced. The as-prepared N-doped Co(OH)F-CFP (N:Co(OH)F-CFP) has excellent hydrophilicity, which facilitates its contact with the electrolyte and then accelerates the passing of electrons back and forth between the surface of the material and the electrolyte. Under alkaline conditions, N:Co(OH)F-CFP's OER activity is superior to that of IrO2 . Its potential can reach 1.540 V ( vs. RHE) at 10 mA cm −2 with a Tafel slope of 69.75 mV dec −1 in 1 M KOH solution.