Dynamic behaviour in nonporous hybrid metal–organic materials via mechanochemical and gas–solid reactions. Issue 42 (10th October 2018)

• Record Type: Journal Article
• Authors: Guo, Fang; Wang, Hao-Cheng; Famulari, Antonino; Lu, Hai-Dong; Martí-Rujas, Javier
• Is Part Of: CrystEngComm. Volume 20:Issue 42(2018)
• Page Start: 6721
• Page End: 6726
• Publication Date: 2018-10-10
• Subjects: Crystals -- Periodicals; Crystal growth -- Periodicals; Crystallography -- Periodicals; Cristaux -- Périodiques; Cristaux -- Croissance -- Périodiques; Cristallographie -- Périodiques; 548
• DOI: 10.1039/c8ce01287c
• Languages: English
• ISSNs: 1466-8033

Abstract

Abstract : Nonporous hybrid metal organic materials have been studied in the solid-state by mechanochemical reactions, chemisorption and release of HCl by heating. The dynamic behavior of the hybrid materials allows the breaking and formation of chemical bonds. Abstract : Nonporous hybrid metal–organic materials self-assembled by a ditopic organic ligand and copper(ii ) have shown a dynamic behavior by releasing and trapping HCl. The solid-state process involves major structural reorganizations comprising cleavage and formation of coordination and covalent chemical bonds by mechanochemical reactions, heating reactions or chemisorption. Single crystal X-ray diffraction, powder X-ray diffraction and TGA in combination with DFT specific for solid-state systems have been used to study the solid-state reactivity.