Toward Platinum Group Metal-Free Catalysts for Hydrogen/Air Proton-Exchange Membrane Fuel Cells. Issue 2 (1st April 2018)

• Record Type: Journal Article
• Authors: Jaouen, Frédéric; Jones, Deborah; Coutard, Nathan; Artero, Vincent; Strasser, Peter; Kucernak, Anthony
• Is Part Of: Johnson Matthey technology review. Volume 62:Issue 2(2018:Apr.)
• Page Start: 231
• Page End: 255
• Publication Date: 2018-04-01
• Subjects: Technology -- Periodicals; Chemical engineering -- Periodicals; Metallurgy -- Periodicals; Materials -- Periodicals; Research, Industrial -- Periodicals; Periodicals; 605
• DOI: 10.1595/205651318X696828
• Languages: English
• ISSNs: 2056-5135

Abstract

The status, concepts and challenges toward catalysts free of platinum group metal (pgm) elements for proton-exchange membrane fuel cells (PEMFC) are reviewed. Due to the limited reserves of noble metals in the Earth's crust, a major challenge for the worldwide development of PEMFC technology is to replace Pt with pgm-free catalysts with sufficient activity and stability. The priority target is the substitution of cathode catalysts (oxygen reduction) that account for more than 80% of pgms in current PEMFCs. Regarding hydrogen oxidation at the anode, ultralow Pt content electrodes have demonstrated good performance, but alternative non-pgm anode catalysts are desirable to increase fuel cell robustness, decrease the H2 purity requirements and ease the transition from H2 derived from natural gas to H2 produced from water and renewable energy sources.