Role of molybdenum in corrosion of iron‐based alloys in contact with hydrogen sulfide containing solution. Issue 6 (9th November 2016)

• Record Type: Journal Article
• Authors: Genchev, G.; Bosch, C.; Wanzenberg, E.; Erbe, A.
• Is Part Of: Materials and corrosion. Volume 68:Issue 6(2017)
• Page Start: 595
• Page End: 603
• Publication Date: 2016-11-09
• Subjects: chloride -- corrosion rate -- hydrogen sulfide -- integrated corrosion rate -- iron -- molybdenum -- polarization -- sour gas -- weight loss; Materials -- Periodicals; Metals -- Periodicals; Corrosion and anti-corrosives -- Periodicals; 620.1122305
• DOI: 10.1002/maco.201609247
• Languages: English
• ISSNs: 0947-5117

Abstract

Abstract : A sample iron molybdenum alloy with 3.4 wt% (2 at%) molybdenum, and pure iron, are exposed to hydrogen sulfide saturated saline solution for up to 56 days. In addition, their behavior under anodic polarization in the same electrolyte is investigated. The initially fast dissolution of the iron molybdenum alloy slows down significantly over time, while iron corrodes with a constant rate. The observed slow down of the corrosion rate can be described well with an exponential decay of the instantaneous corrosion rate with a time constant of (0.15 ± 0.03)/day, which implies stop in corrosion in practical terms after ≈ 2 weeks. Relationships are discussed between the instantaneous corrosion rate, and the time‐averaged integral corrosion rate. Dissolution under anodic polarization of the iron molybdenum alloy is slower than for pure iron. While at certain times, pyrite, FeS2, is found as corrosion product, the main corrosion product is mackinawite, FeS. The latter likely contains a certain fraction of molybdenum in case of the iron molybdenum alloy. On iron molybdenum, corrosion products forming a sealing layer are observed, which slow down further corrosion. The corrosion products on iron molybdenum show better adhesion to the base material surface. Abstract : Molybdenum has been used to reduce the susceptibility of certain steels to sour gas corrosion, i.e., corrosion in hydrogen sulfide, H2 S, containing environments. This work uses a model alloy to show that addition of molybdenum stops the dissolution of iron almost completely under sour gas conditions.