Synthesis of C70‐Based Fluorophores through Sequential Functionalization to Form Isomerically Pure Multiadducts. (27th January 2017)
- Record Type:
- Journal Article
- Title:
- Synthesis of C70‐Based Fluorophores through Sequential Functionalization to Form Isomerically Pure Multiadducts. (27th January 2017)
- Main Title:
- Synthesis of C70‐Based Fluorophores through Sequential Functionalization to Form Isomerically Pure Multiadducts
- Authors:
- Lou, Ning
Li, Yanbang
Gan, Liangbing - Abstract:
- Abstract: Selective addition to the C70 cage divides its π‐conjugated system into various smaller π‐conjugated systems with enhanced fluorescent properties. Key reactions include chlorination, methoxylation, ozonation, and Bingel or Bingel–Hirsch reactions. The maximum emission wavelength of the C70 multiadducts ranges from 450 to 655 nm. Among the C70 multiadducts, C70 (OMe)8 (C(COOEt)2 )3 showed the highest quantum yield ( Φ F =0.18) and the largest Δ[ λ max (emission)− λ max (absorption)] (402 nm), with maximum emission at 655 nm.
- Is Part Of:
- Angewandte Chemie. Volume 129:Number 9(2017)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 129:Number 9(2017)
- Issue Display:
- Volume 129, Issue 9 (2017)
- Year:
- 2017
- Volume:
- 129
- Issue:
- 9
- Issue Sort Value:
- 2017-0129-0009-0000
- Page Start:
- 2443
- Page End:
- 2447
- Publication Date:
- 2017-01-27
- Subjects:
- Fluorophore -- Fullerene -- Ozonierung -- Quantenpunkte
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201612054 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 8304.xml