Direct Syn Addition of Two Silicon Atoms to a C≡C Triple Bond by Si−Si Bond Activation: Access to Reactive Disilylated Olefins. (23rd January 2017)
- Record Type:
- Journal Article
- Title:
- Direct Syn Addition of Two Silicon Atoms to a C≡C Triple Bond by Si−Si Bond Activation: Access to Reactive Disilylated Olefins. (23rd January 2017)
- Main Title:
- Direct Syn Addition of Two Silicon Atoms to a C≡C Triple Bond by Si−Si Bond Activation: Access to Reactive Disilylated Olefins
- Authors:
- Ahmad, Maha
Gaumont, Annie‐Claude
Durandetti, Muriel
Maddaluno, Jacques - Abstract:
- Abstract: A catalytic intramolecular silapalladation of alkynes affords, in good yields and stereoselectively, syn ‐disilylated heterocycles of different chemical structure and size. When applied to silylethers, this reaction leads to vinylic silanols that undergo a rhodium‐catalyzed addition to activated olefins, providing the oxa‐Heck or oxa‐Michael products, depending on the reaction conditions.
- Is Part Of:
- Angewandte Chemie. Volume 129:Number 9(2017)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 129:Number 9(2017)
- Issue Display:
- Volume 129, Issue 9 (2017)
- Year:
- 2017
- Volume:
- 129
- Issue:
- 9
- Issue Sort Value:
- 2017-0129-0009-0000
- Page Start:
- 2504
- Page End:
- 2508
- Publication Date:
- 2017-01-23
- Subjects:
- Cyclisierungen -- Disilane -- Heterocyclen -- Palladium -- Vinylsilane
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201611719 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 8304.xml