Back Cover: Synthesis of Tetrazino‐tetrazine 1, 3, 6, 8‐Tetraoxide (TTTO) (Angew. Chem. Int. Ed. 38/2016). Issue 38 (3rd August 2016)

• Record Type: Journal Article
• Authors: Klenov, Michael S.; Guskov, Alexey A.; Anikin, Oleg V.; Churakov, Aleksandr M.; Strelenko, Yurii A.; Fedyanin, Ivan V.; Lyssenko, Konstantin A.; Tartakovsky, Vladimir A.
• Is Part Of: Angewandte Chemie international edition. Volume 55:Issue 38(2016)
• Page Start: 11688
• Page End: 11688
• Publication Date: 2016-08-03
• Subjects: cyclization -- energetic materials -- nitrogen heterocycles -- tetrazines -- total synthesis; Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201606541
• Languages: English
• ISSNs: 1433-7851

Abstract

Abstract : A high‐energy molecule can be thermally stable if its structure shows alternating charges. In their Communication onpage 11472 ff., A. M. Churakov et al. report the synthesis of a new nitrogen system 1, 2, 3, 4‐tetrazino[5, 6‐ e ]‐1, 2, 3, 4‐tetrazine‐1, 3, 6, 8‐tetraoxide. The synthetic strategy was based on the sequential closure of two 1, 2, 3, 4‐tetrazine 1, 3‐dioxide rings by the generation of oxodiazonium ions and their intramolecular coupling with tert ‐butyl‐ NNO ‐azoxy groups.