Nickel(0)‐Mediated Transformation of Tetrafluoroethylene and Vinylarenes into Fluorinated Cyclobutyl Compounds. (23rd January 2017)
- Record Type:
- Journal Article
- Title:
- Nickel(0)‐Mediated Transformation of Tetrafluoroethylene and Vinylarenes into Fluorinated Cyclobutyl Compounds. (23rd January 2017)
- Main Title:
- Nickel(0)‐Mediated Transformation of Tetrafluoroethylene and Vinylarenes into Fluorinated Cyclobutyl Compounds
- Authors:
- Ohashi, Masato
Ueda, Yuta
Ogoshi, Sensuke - Abstract:
- Abstract: In the presence of Ni 0 /PCy3, styrene was found to participate in oxidative cyclization with tetrafluoroethylene, thus leading to the corresponding nickelacycle with a unique η 3 ‐π‐benzyl structure. In addition, the flexibility of the coordination mode in the η 3 ‐benzyl moiety allowed the partially fluorinated nickelacycle to undergo unprecedented amine‐induced α‐fluorine elimination, thus leading to the construction of a fluorinated cyclobutyl skeleton.
- Is Part Of:
- Angewandte Chemie. Volume 129:Number 9(2017)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 129:Number 9(2017)
- Issue Display:
- Volume 129, Issue 9 (2017)
- Year:
- 2017
- Volume:
- 129
- Issue:
- 9
- Issue Sort Value:
- 2017-0129-0009-0000
- Page Start:
- 2475
- Page End:
- 2479
- Publication Date:
- 2017-01-23
- Subjects:
- Amine -- Fluor -- Nickel -- Reaktionsmechanismen -- Synthesemethoden
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201610047 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 8304.xml