De Novo Synthesis of Furanose Sugars: Catalytic Asymmetric Synthesis of Apiose and Apiose‐Containing Oligosaccharides. (6th July 2016)
- Record Type:
- Journal Article
- Title:
- De Novo Synthesis of Furanose Sugars: Catalytic Asymmetric Synthesis of Apiose and Apiose‐Containing Oligosaccharides. (6th July 2016)
- Main Title:
- De Novo Synthesis of Furanose Sugars: Catalytic Asymmetric Synthesis of Apiose and Apiose‐Containing Oligosaccharides
- Authors:
- Kim, Mijin
Kang, Soyeong
Rhee, Young Ho - Abstract:
- Abstract: A de novo synthetic method towards apiose, a structurally unusual furanose, is reported. The key feature is sequential metal catalysis consisting of the palladium‐catalyzed asymmetric intermolecular hydroalkoxylation of an alkoxyallene and subsequent ring‐closing metathesis (RCM). This strategy enabled the efficient synthesis of various apiose‐containing disaccharides and a unique convergent synthesis of trisaccharides.
- Is Part Of:
- Angewandte Chemie. Volume 128:Number 33(2016)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 128:Number 33(2016)
- Issue Display:
- Volume 128, Issue 33 (2016)
- Year:
- 2016
- Volume:
- 128
- Issue:
- 33
- Issue Sort Value:
- 2016-0128-0033-0000
- Page Start:
- 9885
- Page End:
- 9889
- Publication Date:
- 2016-07-06
- Subjects:
- Asymmetrische Synthesen -- Kohlenhydrate -- De-novo-Synthesen -- Diastereoselektivität -- Oligosaccharide
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201604199 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 8315.xml