Palladium‐Catalyzed Fluorosulfonylvinylation of Organic Iodides. (29th March 2017)
- Record Type:
- Journal Article
- Title:
- Palladium‐Catalyzed Fluorosulfonylvinylation of Organic Iodides. (29th March 2017)
- Main Title:
- Palladium‐Catalyzed Fluorosulfonylvinylation of Organic Iodides
- Authors:
- Zha, Gao‐Feng
Zheng, Qinheng
Leng, Jing
Wu, Peng
Qin, Hua‐Li
Sharpless, K. Barry - Abstract:
- Abstract: A palladium‐catalyzed fluorosulfonylvinylation reaction of organic iodides is described. Catalytic Pd(OAc)2 with a stoichiometric amount of silver(I) trifluoroacetate enables the coupling process between either an (hetero)aryl or alkenyl iodide with ethenesulfonyl fluoride (ESF). The method is demonstrated in the successful syntheses of eighty‐eight otherwise difficult to access compounds, in up to 99 % yields, including the unprecedented 2‐heteroarylethenesulfonyl fluorides and 1, 3‐dienylsulfonyl fluorides.
- Is Part Of:
- Angewandte Chemie. Volume 129:Number 17(2017)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 129:Number 17(2017)
- Issue Display:
- Volume 129, Issue 17 (2017)
- Year:
- 2017
- Volume:
- 129
- Issue:
- 17
- Issue Sort Value:
- 2017-0129-0017-0000
- Page Start:
- 4927
- Page End:
- 4930
- Publication Date:
- 2017-03-29
- Subjects:
- Alkene -- Fluor -- Klick-Chemie -- Palladium -- Wirkstoffsuche
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201701162 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 8268.xml