Frontispiece: Excited State N−H Tautomer Selectivity in the Singlet Energy Transfer of a Zinc(II)‐Porphyrin–Truxene–Corrole Assembly. Issue 21 (12th April 2017)

• Record Type: Journal Article
• Authors: Langlois, Adam; Xu, Hai‐Jun; Karsenti, Paul‐Ludovic; Gros, Claude P.; Harvey, Pierre D.
• Is Part Of: Chemistry. Volume 23:Issue 21(2017)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2017-04-12
• Subjects: corroles -- Dexter energy transfer -- FRET -- tautomerization -- truxene; Chemistry -- Periodicals; 540
• DOI: 10.1002/chem.201782163
• Languages: English
• ISSNs: 0947-6539

Abstract

Abstract : An original corrole‐containing polyad for S1 energy transfer, in which one zinc(II)porphyrin donor is linked to two free base corrole acceptors by a truxene linker, is reported. This polyad exhibits a rapid zinc(II) porphyrin*→free‐base corrole transfer, even faster than the tautomerization in the excited state processes taking advantage of the good electronic communication provided by the truxene bridge. For more details see the Full Paper by C. P. Gros, P. D. Harvey et al. onpage 5010 ff.