Factors affecting the chemical composition of snowpack in the Kilpisjärvi area of North Scandinavia. (October 2015)

• Record Type: Journal Article
• Authors: Raidla, Valle; Kaup, Enn; Ivask, Jüri
• Is Part Of: Atmospheric environment. Volume 118(2015)
• Page Start: 211
• Page End: 218
• Publication Date: 2015-10
• Subjects: pH of snow -- Sea salts -- Terrestrial dust -- Arctic; Air -- Pollution -- Periodicals; Air -- Pollution -- Meteorological aspects -- Periodicals; 551.51
• DOI: 10.1016/j.atmosenv.2015.07.043
• Languages: English
• ISSNs: 1352-2310

Abstract

Abstract: Kilpisjärvi is a remote area in northwest Finland, almost without any local human impact on the environment. The design of the study was to investigate the chemical composition of local precipitation in the Kilpisjärvi region and determine the factors influencing it. To this aim, we collected 29 snow samples from the Lake Saana catchment and its surroundings in spring of 2008 and 2009. Already within the radius of a few hundred metres, significant chemical heterogeneity could be detected in the snow cover, caused by mixed marine and terrestrial precipitation and the impact of local rock dust. Based on the Cl − /Ca 2+ ratio in snow, this could occur in localised areas, where marine or terrestrial aerosols predominate. Clear correlation was noted between SO 4 2 − and Ca 2+, induced possibly by recombination of SO 4 2 − with carbonaceous dust. Other factors, such as nitrification in snow cover, could also have affected the pH levels of snow, which are mostly controlled by carbonate dust. Highlights: The snow's chemistry showed notable variations in space and time on a narrow area. The pH of snow is mainly controlled by carbonate dust. The occurrence of Ca 2+ and SO 4 2 − in snow can be linked to aerosol modification. The snow's chemistry depends on local topography.