Li+ Ion Transport in Polymer Electrolytes Based on a Glyme-Li Salt Solvate Ionic Liquid. (1st September 2015)

• Record Type: Journal Article
• Authors: Kido, Ryosuke; Ueno, Kazuhide; Iwata, Kaori; Kitazawa, Yuzo; Imaizumi, Satoru; Mandai, Toshihiko; Dokko, Kaoru; Watanabe, Masayoshi
• Is Part Of: Electrochimica acta. Volume 175(2015)
• Page Start: 5
• Page End: 12
• Publication Date: 2015-09-01
• Subjects: solvate ionic liquid -- polymer electrolyte -- polymer-in-salt -- ionicity -- glyme; Electrochemistry -- Periodicals; Electrochemistry, Industrial -- Periodicals; 541.37
• DOI: 10.1016/j.electacta.2015.01.067
• Languages: English
• ISSNs: 0013-4686

Abstract

Graphical abstract: ABSTRACT: Polymer electrolytes (PEs) have served as the focus of intensive research as new ion-conducting materials, especially for lithium battery applications. A new strategy to develop fast lithium-conducting PEs is reported here. The thermal, ionic transport, and electrochemical properties of polymer solutions in a glyme-Li salt solvate ionic liquid, [Li(G4)1 ][TFSA], composed of an equimolar mixture of lithium bis(trifluoromethanesulfonyl) amide (Li[TFSA]) and tetraglyme (G4), were characterized. Poly(ethylene oxide) (PEO), poly(methyl methacrylate) (PMMA), and poly(butyl acrylate) (PBA) were combined with [Li(G4)1 ][TFSA] in order to explore the effects of polymer structure on the properties. The self-diffusion coefficient ratio of the glyme and Li + ions ( D G / D Li ) was investigated to evaluate the stability of the complex (solvate) cations. The D G / D Li values suggested that the [Li(G4)1 ] + complex cations underwent a ligand exchange reaction between G4 and PEO in the PEO-based solution, whereas the cations remained stable ( D G / D Li = 1) in the PMMA- and PBA-based solutions. The robustness of the [Li(G4)1 ] + complex cations in the PMMA- and PBA-based solutions was reflected in high weight-loss temperature, greater Li transference number, and high oxidative stability. Owing to the lower glass transition temperature and low affinity towards Li + ions, the PBA-based solutions yielded superior lithium transport properties (ionic conductivity of 10 −4 ∼10 −3 Scm −1 and Li transference number as high as 0.5) among the investigated polymer solutions.