Palladium‐Catalyzed Enantioselective Redox‐Relay Heck Alkynylation of Alkenols To Access Propargylic Stereocenters. (3rd May 2017)
- Record Type:
- Journal Article
- Title:
- Palladium‐Catalyzed Enantioselective Redox‐Relay Heck Alkynylation of Alkenols To Access Propargylic Stereocenters. (3rd May 2017)
- Main Title:
- Palladium‐Catalyzed Enantioselective Redox‐Relay Heck Alkynylation of Alkenols To Access Propargylic Stereocenters
- Authors:
- Chen, Zhi‐Min
Nervig, Christine S.
DeLuca, Ryan J.
Sigman, Matthew S. - Abstract:
- Abstract: An enantioselective redox‐relay Heck alkynylation of di‐ and trisubstituted alkenols to construct propargylic stereocenters is disclosed using a new pyridine oxazoline ligand. This strategy allows direct access to chiral β‐alkynyl carbonyl compounds employing allylic alcohol substrates in contrast to more traditional conjugate addition methods.
- Is Part Of:
- Angewandte Chemie. Volume 129:Number 23(2017)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 129:Number 23(2017)
- Issue Display:
- Volume 129, Issue 23 (2017)
- Year:
- 2017
- Volume:
- 129
- Issue:
- 23
- Issue Sort Value:
- 2017-0129-0023-0000
- Page Start:
- 6751
- Page End:
- 6754
- Publication Date:
- 2017-05-03
- Subjects:
- Alkene -- Alkinylierung -- Heck-Reaktion -- Propargylisches Stereozentrum
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201703089 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 8115.xml