A Rhodium(II)‐Catalyzed Formal [4+1]‐Cycloaddition toward Spirooxindole Pyrrolone Construction Employing Vinyl Isocyanates as 1, 4‐Dipoles. (3rd May 2017)
- Record Type:
- Journal Article
- Title:
- A Rhodium(II)‐Catalyzed Formal [4+1]‐Cycloaddition toward Spirooxindole Pyrrolone Construction Employing Vinyl Isocyanates as 1, 4‐Dipoles. (3rd May 2017)
- Main Title:
- A Rhodium(II)‐Catalyzed Formal [4+1]‐Cycloaddition toward Spirooxindole Pyrrolone Construction Employing Vinyl Isocyanates as 1, 4‐Dipoles
- Authors:
- Meloche, Jennifer L.
Ashfeld, Brandon L. - Abstract:
- Abstract: A Rh II ‐catalyzed, formal [4+1]‐cycloaddition between diazooxindoles as electrophilic C1 synthons and 1, 3‐heterodienes for the construction of spirooxindole pyrrolones is described. Employing vinyl isocyanates as 1, 4‐dipoles, the cycloannulation occurs under relatively mild conditions and provides the corresponding pyrrolones in good to excellent yields.
- Is Part Of:
- Angewandte Chemie. Volume 129:Number 23(2017)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 129:Number 23(2017)
- Issue Display:
- Volume 129, Issue 23 (2017)
- Year:
- 2017
- Volume:
- 129
- Issue:
- 23
- Issue Sort Value:
- 2017-0129-0023-0000
- Page Start:
- 6704
- Page End:
- 6708
- Publication Date:
- 2017-05-03
- Subjects:
- [4+1]-Cycloadditionen -- Cyclopropanumlagerung -- Diazooxindole -- Spirooxindol-Alkaloide -- Vinylisocyanate
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201701147 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 8116.xml